Chapter 19, Problem 82a
Consider the reaction PbCO3(s) ⇌ PbO(s) + CO2(g) Using data in Appendix C, calculate the equilibrium pressure of CO2 in the system at (a) 400 °C.
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Using data from Appendix C, write the equilibrium-constant expression and calculate the value of the equilibrium constant and the free-energy change for these reactions at 298 K: (a) NaHCO3(s) ⇌ NaOH(s) + CO2(g)
Consider the decomposition of barium carbonate: BaCO3(s) ⇌ BaO(s) + CO2(g) Using data from Appendix C, calculate the equilibrium pressure of CO2 at (a) 298 K.
Consider the decomposition of barium carbonate: BaCO3(s) ⇌ BaO(s) + CO2(g) Using data from Appendix C, calculate the equilibrium pressure of CO2 at (b) 1100 K.
The value of Ka for nitrous acid (HNO2) at 25 °C is given in Appendix D. (a) Write the chemical equation for the equilibrium that corresponds to Ka.
The value of Ka for nitrous acid (HNO2) at 25 °C is given in Appendix D. (b) By using the value of Ka, calculate ΔG° for the dissociation of nitrous acid in aqueous solution.
The value of Ka for nitrous acid (HNO2) at 25 °C is given in Appendix D. (c) What is the value of ΔG at equilibrium?