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Ch.19 - Chemical Thermodynamics

Chapter 19, Problem 19

Consider a system consisting of an ice cube. (a) Under what conditions can the ice cube melt reversibly?

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Hello everyone. So in this video we're trying to identify the conditions as to when R. B. R. Two s will go ahead and melt reversible. E. So we're talking about this term reversible. We what does this mean? It means that we want our reaction to be at equilibrium. So if you want our reaction to be at equilibrium, it means that our delta G. Which is our gibbs free energy will equal to zero. So reversible means we're at equilibrium. And if we are at equilibrium our delta G value will equal to zero. So the equation that we have for this reaction is that R. B. R. Two which is a solid that we said we'll go ahead and go to your BR two and it's liquid faith a solid. We're going to assume that it's at freezing point because we're given this temperature here in the problem. So this means that at the freezing point of course at equilibrium it will also equal to the melting point. Were given the freezing point but we're not giving the melting point. And of course normal conditions, normal conditions meaning standard conditions, our pressure will equal to one A. T. M. So then the conditions that BR two solid will amount reversible. E at is when the pressure is equal to one A. T. M. And the T. Which is for temperature is equal to negative 7.2°C. And this is the final answer for this problem. Thank you all so much for watching
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Textbook Question

Consider a process in which an ideal gas changes from state 1 to state 2 in such a way that its temperature changes from 300 K to 200 K. (b) Is this process isothermal?

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Textbook Question

Consider a process in which an ideal gas changes from state 1 to state 2 in such a way that its temperature changes from 300 K to 200 K. (c) Does the change in the internal energy, ΔE, depend on the particular pathway taken to carry out this change of state?

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Textbook Question

A system goes from state 1 to state 2 and back to state 1. (c) Suppose the changes in state are reversible processes. Is the work done by the system upon going from state 1 to state 2 the same or different as compared to that upon going from state 2 back to state 1?

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Textbook Question

Indicate whether each statement is true or false. (a) ΔS is a state function. (b) If a system undergoes a reversible change, the entropy of the universe increases. (c) If a system undergoes a reversible process, the change in entropy of the system is exactly matched by an equal and opposite change in the entropy of the surroundings. (d) If a system undergoes a reversible process, the entropy change of the system must be zero.

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Textbook Question

The normal boiling point of Br2(l) is 58.8 °C, and its molar enthalpy of vaporization is ΔHvap = 29.6 kJ/mol. (a) When Br2(l) boils at its normal boiling point, does its entropy increase or decrease?

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Textbook Question

The normal boiling point of Br2(𝑙) is 58.8  °C, and its molar enthalpy of vaporization is Δ𝐻vap=29.6 kJ/mol. (b) Calculate the value of Δ𝑆 when 1.00 mol of Br2(𝑙) is vaporized at 58.8  °C.

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