Chapter 19, Problem 19
Consider a system consisting of an ice cube. (a) Under what conditions can the ice cube melt reversibly?
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Consider a process in which an ideal gas changes from state 1 to state 2 in such a way that its temperature changes from 300 K to 200 K. (b) Is this process isothermal?
Consider a process in which an ideal gas changes from state 1 to state 2 in such a way that its temperature changes from 300 K to 200 K. (c) Does the change in the internal energy, ΔE, depend on the particular pathway taken to carry out this change of state?
A system goes from state 1 to state 2 and back to state 1. (c) Suppose the changes in state are reversible processes. Is the work done by the system upon going from state 1 to state 2 the same or different as compared to that upon going from state 2 back to state 1?
Indicate whether each statement is true or false. (a) ΔS is a state function. (b) If a system undergoes a reversible change, the entropy of the universe increases. (c) If a system undergoes a reversible process, the change in entropy of the system is exactly matched by an equal and opposite change in the entropy of the surroundings. (d) If a system undergoes a reversible process, the entropy change of the system must be zero.
The normal boiling point of Br2(l) is 58.8 °C, and its molar enthalpy of vaporization is ΔHvap = 29.6 kJ/mol. (a) When Br2(l) boils at its normal boiling point, does its entropy increase or decrease?
The normal boiling point of Br2(𝑙) is 58.8 °C, and its molar enthalpy of vaporization is Δ𝐻vap=29.6 kJ/mol. (b) Calculate the value of Δ𝑆 when 1.00 mol of Br2(𝑙) is vaporized at 58.8 °C.