Skip to main content
Ch.16 - Acid-Base Equilibria
Chapter 16, Problem 109a

Butyric acid is responsible for the foul smell of rancid butter. The pKa of butyric acid is 4.84. (a) Calculate the pKb for the butyrate ion.

Verified Solution

Video duration:
1m
This video solution was recommended by our tutors as helpful for the problem above.
Was this helpful?

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

pKa and pKb Relationship

The pKa and pKb values are related through the equation pKa + pKb = 14 at 25°C. This relationship allows us to convert between the acidity of a weak acid and the basicity of its conjugate base. In this case, butyric acid has a pKa of 4.84, which can be used to find the pKb of the butyrate ion.
Recommended video:
Guided course
03:01
Ka and Kb Relationship

Acid-Base Equilibrium

Acid-base equilibrium describes the balance between an acid and its conjugate base in solution. For butyric acid, the equilibrium can be represented as HA ⇌ H⁺ + A⁻, where HA is the acid and A⁻ is the conjugate base (butyrate ion). Understanding this equilibrium is essential for calculating pKb from pKa.
Recommended video:
Guided course
05:11
Triprotic Acid Equilibrium

Conjugate Acid-Base Pairs

Conjugate acid-base pairs consist of an acid and its corresponding base that differ by a proton (H⁺). In this scenario, butyric acid (the acid) and butyrate ion (the base) form a conjugate pair. Recognizing these pairs is crucial for applying the pKa and pKb relationship effectively.
Recommended video:
Guided course
01:30
Conjugate Acid-Base Pairs