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Ch.13 - Properties of Solutions
Chapter 13, Problem 7

The structures of vitamins E and B6 are shown below. Predict which is more water soluble and which is more fat soluble. [Section 13.3]

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Solubility Principles

Solubility refers to the ability of a substance to dissolve in a solvent. Water solubility is influenced by the presence of polar functional groups, which interact favorably with water molecules, while fat solubility is associated with nonpolar characteristics that dissolve in lipids. Understanding these principles helps predict how vitamins behave in biological systems.
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Chemical Structure of Vitamins

The chemical structure of vitamins, including the presence of functional groups such as hydroxyl (-OH) or carboxyl (-COOH), plays a crucial role in determining their solubility. For instance, vitamins with more hydrophilic groups tend to be more water-soluble, while those with long hydrocarbon chains are typically more fat-soluble. Analyzing the structures of vitamins E and B6 is essential for making solubility predictions.
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Hydrophilic vs. Hydrophobic

Hydrophilic substances are attracted to water and tend to dissolve in it, while hydrophobic substances repel water and are more soluble in fats. This distinction is vital when predicting the solubility of vitamins, as it directly relates to their functional roles in the body. Recognizing which vitamin has hydrophilic or hydrophobic characteristics aids in understanding their absorption and transport mechanisms.
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Related Practice
Textbook Question

This figure shows the interaction of a cation with surrounding water molecules. (b) Which of the following explanations accounts for the fact that the ion–solvent interaction is greater for Li+ than for K+? a. Li+ is of lower mass than K+. b. The ionization energy of Li is higher than that for K. c. Li+ has a smaller ionic radius than K+. d. Li has a lower density than K. e. Li reacts with water more slowly than K. [Section 13.1]

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Textbook Question

Consider two ionic solids, both composed of singly charged ions, that have different lattice energies. (b) If not, which solid will be more soluble in water, the one with the larger lattice energy or the one with the smaller lattice energy? Assume that solute–solvent interactions are the same for both solids. [Section 13.1]

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Textbook Question

The figure shows two identical volumetric flasks containing the same solution at two temperatures. (b) Does the molality of the solution change with the change in temperature? [Section 13.4]

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Textbook Question

This portion of a phase diagram shows the vapor–pressure curves of a volatile solvent and of a solution of that solvent containing a nonvolatile solute. (b) What are the normal boiling points of the solvent and the solution? [Section 13.5]

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Textbook Question

Suppose you had a balloon made of some highly flexible semipermeable membrane. The balloon is filled completely with a 0.2 M solution of some solute and is submerged in a 0.1 M solution of the same solute:

Initially, the volume of solution in the balloon is 0.25 L. Assuming the volume outside the semipermeable membrane is large, as the illustration shows, what would you expect for the solution volume inside the balloon once the system has come to equilibrium through osmosis? [Section 13.5]

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