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Ch.13 - Properties of Solutions

Chapter 13, Problem 7

The structures of vitamins E and B6 are shown below. Predict which is more water soluble and which is more fat soluble. [Section 13.3]

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Welcome back everyone in this example, we need to determine which of the following vitamins is water soluble and or fat soluble. So looking at vitamin D, we can see we have a very large molecular structure of hydrocarbons, recall that each corner represents carbon atoms and each of these carbon atoms should have four bonds where one of the bonds should be hydrogen. Now, comparing our electro negativity between the carbon atoms and hydrogen and these structures, we should recognize for example, this carbon atom is bonded to two hydrogen atoms which are implied, but we're drawing them in now and recall that carbon is more electro negative than hydrogen on our periodic table. So carbon is going to have that slightly negative dipole, whereas our hydrogen atoms will have the slightly positive di pole there. If we recognize that our electro negativity trend increases as we go towards the top, right towards flooring on our product table. What we just outlined will make sense and because we have these disciples throughout this entire molecule of vitamin D. Due to the presence of the carbon and hydrogen atoms that make up the structure, we're going to say that we have strong dispersion forces. Since this is again a long hydrocarbon chain and these dispersion forces are not going to be a match to be able to fight against the forces in our water molecule. Because we should recall that water has hydrogen bonding and recall that hydrogen bonding is a very strong inter molecular force. So we're going to need something even stronger than just dispersion forces, meaning that we can say that vitamin D. Is going to be fat soluble since it won't dissolve in water, it should dissolve a fat. And so this is going to be our first answer for vitamin D. Now we want to focus on vitamin C. And we should recognize that when it comes to vitamin C, we have a total of four alcohol groups which allows it to have a lot of the inter molecular force being hydrogen bonding. Since it has the presence of hydrogen, and this is a much smaller molecule. Since we have such a rich presence of the inter molecular force being hydrogen bonding, vitamin C should definitely be able to be dissolved in water. And so we would say that vitamin C is also, or in this case is going to be water soluble more than being fat soluble. And so for our final answers, we have that vitamin C is water soluble and vitamin D. Is going to be fat soluble. So I hope that everything I outlined was clear. If you have any questions, leave them down below and I'll see everyone in the next practice video
Related Practice
Textbook Question

This figure shows the interaction of a cation with surrounding water molecules. (b) Which of the following explanations accounts for the fact that the ion–solvent interaction is greater for Li+ than for K+? a. Li+ is of lower mass than K+. b. The ionization energy of Li is higher than that for K. c. Li+ has a smaller ionic radius than K+. d. Li has a lower density than K. e. Li reacts with water more slowly than K. [Section 13.1]

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Textbook Question

Consider two ionic solids, both composed of singly charged ions, that have different lattice energies. (b) If not, which solid will be more soluble in water, the one with the larger lattice energy or the one with the smaller lattice energy? Assume that solute–solvent interactions are the same for both solids. [Section 13.1]

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Textbook Question

The figure shows two identical volumetric flasks containing the same solution at two temperatures. (b) Does the molality of the solution change with the change in temperature? [Section 13.4]

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Textbook Question

This portion of a phase diagram shows the vapor–pressure curves of a volatile solvent and of a solution of that solvent containing a nonvolatile solute. (b) What are the normal boiling points of the solvent and the solution? [Section 13.5]

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Textbook Question

Suppose you had a balloon made of some highly flexible semipermeable membrane. The balloon is filled completely with a 0.2 M solution of some solute and is submerged in a 0.1 M solution of the same solute:

Initially, the volume of solution in the balloon is 0.25 L. Assuming the volume outside the semipermeable membrane is large, as the illustration shows, what would you expect for the solution volume inside the balloon once the system has come to equilibrium through osmosis? [Section 13.5]

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