Chapter 11, Problem 21c
Which member in each pair has the greater dispersion forces?(c) SiH4 or GeH4.
Video transcript
True or false: (b) For the noble gases the dispersion forces decrease while the boiling points increase as you go down the column in the periodic table.
True or false: (e) The larger the atom, the more polarizable it is.
Which member in each pair has the greater dispersion forces? (a) H2O or H2S,
Which member in each pair has the stronger intermolecular dispersion forces? (c) CH3CH2CH2Cl or (CH3)2CHCl
(b) Which of the following molecules can form hydrogen bonds with other molecules of the same kind: CH3F, CH3NH2, CH3OH, CH3Br?
Ethylene glycol (HOCH2CH2OH), the major substance in antifreeze, has a normal boiling point of 198 °C. By comparison, ethyl alcohol (CH3CH2OH) boils at 78 °C at atmospheric pressure. Ethylene glycol dimethyl ether (CH3OCH2CH2OCH3) has a normal boiling point of 83 °C, and ethyl methyl ether (CH3CH2OCH3) has a nomral boiling point of 11 °C. (a) Explain why replacement of a hydrogen on the oxygen by a CH3 group generally results in a lower boiling point.