Suppose you have two 1-L flasks, one containing N2 at STP, the other containing CH4 at STP. How do these systems compare with respect to (c) average kinetic energy of the molecules?
(c) Calculate the most probable speeds of CO molecules at 300 K.
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Verified Solution
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Key Concepts
Kinetic Molecular Theory
Maxwell-Boltzmann Distribution
Most Probable Speed Formula
(b) Calculate the rms speed of NF3 molecules at 25 °C.
(c) Calculate the most probable speed of an ozone molecule in the stratosphere, where the temperature is 270 K.
(c) Calculate the most probable speeds of Cl2 molecules at 300 K.
Which one or more of the following statements are true? (a) O2 will effuse faster than Cl2. (b) Effusion and diffusion are different names for the same process. (c) Perfume molecules travel to your nose by the process of effusion. (d) The higher the density of a gas, the shorter the mean free path.
At constant pressure, the mean free path 1l2 of a gas molecule is directly proportional to temperature. At constant temperature, l is inversely proportional to pressure. If you compare two different gas molecules at the same temperature and pressure, l is inversely proportional to the square of the diameter of the gas molecules. Put these facts together to create a formula for the mean free path of a gas molecule with a proportionality constant (call it Rmfp, like the ideal-gas constant) and define units for Rmfp.