The graph below shows the change in pressure as the temperature increases for a 1-mol sample of a gas confined to a 1-L container. The four plots correspond to an ideal gas and three real gases: CO2, N2, and Cl2. (a) At room temperature, all three real gases have a pressure less than the ideal gas. Which van der Waals constant, a or b, accounts for the influence intermolecular forces have in lowering the pressure of a real gas?
(b) Which units are appropriate for expressing atmospheric pressures, N, Pa, atm, kg/m2?


Verified Solution

Key Concepts
Units of Pressure
Pascals (Pa)
Atmospheric Pressure
The graph below shows the change in pressure as the temperature increases for a 1-mol sample of a gas confined to a 1-L container. The four plots correspond to an ideal gas and three real gases: CO2, N2, and Cl2. (b) Use the van der Waals constants in Table 10.3 to match the labels in the plot (A, B, and C) with the respective gases 1CO2, N2, and Cl22.
Which of the following statements is false? (a) Gases are far less dense than liquids. (b) Gases are far more compressible than liquids. (c) Because liquid water and liquid carbon tetrachloride do not mix, neither do their vapors. (d) The volume occupied by a gas is determined by the volume of its container.
(c) Which is most likely to be a gas at room temperature and ordinary atmospheric pressure, F2, Br2, K2O?
A person weighing 75 kg is standing on a threelegged stool. The stool momentarily tilts so that the entire weight is on one foot. If the contact area of each foot is 5.0 cm2, calculate the pressure exerted on the underlying surface in (a) bars
A person weighing 75 kg is standing on a threelegged stool. The stool momentarily tilts so that the entire weight is on one foot. If the contact area of each foot is 5.0 cm2, calculate the pressure exerted on the underlying surface in (b) atmospheres