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Ch.10 - Gases
Chapter 10, Problem 74a,b

A sample of 3.00 g of SO2(g) originally in a 5.00-L vessel at 21 °C is transferred to a 10.0-L vessel at 26 °C. A sample of 2.35 g of N2(g) originally in a 2.50-L vessel at 20 °C is transferred to this same 10.0-L vessel. (a) What is the partial pressure of SO2(g) in the larger container? (b) What is the partial pressure of N2(g) in this vessel?

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1
Calculate the number of moles of SO_2 using its mass and molar mass.
Use the ideal gas law, PV = nRT, to find the initial pressure of SO_2 in the 5.00-L vessel.
Determine the new temperature in Kelvin for the 10.0-L vessel.
Apply the ideal gas law again to find the partial pressure of SO_2 in the 10.0-L vessel, using the moles calculated and the new volume and temperature.
Ensure the units are consistent throughout the calculations, especially for R, the ideal gas constant.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ideal Gas Law

The Ideal Gas Law relates the pressure, volume, temperature, and number of moles of a gas through the equation PV = nRT. This law is essential for calculating the behavior of gases under varying conditions, allowing us to determine the partial pressure of a gas when its amount and the conditions of the system are known.
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Partial Pressure

Partial pressure is the pressure exerted by a single component of a gas mixture. According to Dalton's Law of Partial Pressures, the total pressure of a gas mixture is the sum of the partial pressures of each individual gas. Understanding this concept is crucial for calculating the contribution of SO2 to the total pressure in the larger vessel.
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Molar Mass and Mass to Moles Conversion

To find the number of moles of a gas from its mass, the molar mass of the gas is used in the conversion formula: moles = mass (g) / molar mass (g/mol). For SO2, knowing its molar mass (approximately 64.07 g/mol) allows us to convert the given mass into moles, which is necessary for applying the Ideal Gas Law.
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Related Practice
Textbook Question

(a) What are the mole fractions of H2 in a mixture of 15.08 g of O2, 8.17 g of N2, and 2.64 g of H2?

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Textbook Question

(b) What is the partial pressure in atm of each component of this mixture if its held in a 15.50-L vessel at 15 °C?

Textbook Question
A quantity of N2 gas originally held at 531.96 kPa pressure in a 1.00-L container at 26 °C is transferred to a 12.5-L container at 20 °C. A quantity of O2 gas originally at 531.96 kPa and 26 °C in a 5.00-L container is transferred to this same container. What is the total pressure in the new container?
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Textbook Question

A sample of 3.00 g of SO2(g) originally in a 5.00-L vessel at 21 °C is transferred to a 10.0-L vessel at 26 °C. A sample of 2.35 g of N2(g) originally in a 2.50-L vessel at 20 °C is transferred to this same 10.0-L vessel. (c) What is the total pressure in the vessel?

Textbook Question

Determine whether each of the following changes will increase, decrease, or not affect the rate with which gas molecules collide with the walls of their container: (a) increasing the volume of the container (b) increasing the temperature (c) increasing the molar mass of the gas

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Textbook Question

Indicate which of the following statements regarding the kinetic-molecular theory of gases are correct. (a) The average kinetic energy of a collection of gas molecules at a given temperature is proportional to m1/2. (b) The gas molecules are assumed to exert no forces on each other. (c) All the molecules of a gas at a given temperature have the same kinetic energy. (d) The volume of the gas molecules is negligible in comparison to the total volume in which the gas is contained. (e) All gas molecules move with the same speed if they are at the same temperature.

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