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Ch.10 - Gases
Chapter 10, Problem 37a

(a) Calculate the number of molecules in a deep breath of air whose volume is 2.25 L at body temperature, 37 °C, and a pressure of 97.99 kPa.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ideal Gas Law

The Ideal Gas Law is a fundamental equation in chemistry that relates the pressure, volume, temperature, and number of moles of a gas. It is expressed as PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the ideal gas constant, and T is temperature in Kelvin. This law allows us to calculate the number of molecules in a given volume of gas under specific conditions.
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Molar Volume of a Gas

At standard temperature and pressure (STP), one mole of an ideal gas occupies approximately 22.4 liters. However, at different temperatures and pressures, the volume occupied by one mole of gas changes. Understanding how to adjust for these conditions is crucial for calculating the number of molecules in a specific volume of gas, as seen in the context of the question.
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Avogadro's Number

Avogadro's Number, approximately 6.022 x 10²³, is the number of molecules in one mole of a substance. This constant is essential for converting between moles and molecules, allowing chemists to quantify the number of particles in a given sample. In the context of the question, once the number of moles is calculated using the Ideal Gas Law, Avogadro's Number can be used to find the total number of molecules in the air sample.
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Related Practice
Textbook Question
Suppose you are given two 2-L flasks and told that one contains a gas of molar mass 28, the other a gas of molar mass 56, both at the same temperature and pressure. The mass of gas in the flask A is 1.0 g and the mass of gas in the flask B is 2.0 g. Which flask contains the gas of molar mass 28, and which contains the gas of molar mass 56?
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Textbook Question
Suppose you are given two flasks at the same temperature, one of volume 2 L and the other of volume 3 L. The 2-L flask contains 4.8 g of gas, and the gas pressure is x kPa. The 3-L flask contains 0.36 g of gas, and the gas pressure is 0.1x. Do the two gases have the same molar mass? If not, which contains the gas of higher molar mass?
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Textbook Question
Complete the following table for an ideal gas: P V n T 101.33 kPa ? L 3.333 mol 300 K
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Textbook Question

(b) The adult blue whale has a lung capacity of 5.0 * 103 L. Calculate the mass of air (assume an average molar mass of 28.98 g>mol) contained in an adult blue whale's lungs at 0.0 °C and 101.33 kPa, assuming the air behaves ideally.

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Textbook Question

(a) If the pressure exerted by ozone, O3, in the stratosphere is 304 Pa and the temperature is 250 K, how many ozone molecules are in a liter?

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Textbook Question

(b) Carbon dioxide makes up approximately 0.04% of Earth's atmosphere. If you collect a 2.0-L sample from the atmosphere at sea level (101.33 kPa) on a warm day 127 °C2, how many CO2 molecules are in your sample?

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