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Ch.1 - Introduction: Matter, Energy, and Measurement
Chapter 1, Problem 37a

(a) To identify a liquid substance, a student determined its density. Using a graduated cylinder, she measured out a 45-mL sample of the substance. She then measured the mass of the sample, finding that it weighed 38.5 g. She knew that the substance had to be either isopropyl alcohol 1density 0.785 g/mL2 or toluene (density 0.866 g/mL). What are the calculated density and the probable identity of the substance?

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Calculate the density of the liquid using the formula: \( \text{Density} = \frac{\text{Mass}}{\text{Volume}} \).
Substitute the given values into the formula: Mass = 38.5 g and Volume = 45 mL.
Perform the division to find the density of the liquid.
Compare the calculated density with the given densities of isopropyl alcohol (0.785 g/mL) and toluene (0.866 g/mL).
Determine which substance's density is closest to the calculated density to identify the probable substance.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Density Calculation

Density is defined as mass per unit volume, typically expressed in grams per milliliter (g/mL). To calculate the density of a substance, one divides its mass by its volume. In this case, the student measured a mass of 38.5 g and a volume of 45 mL, allowing for the calculation of density using the formula: density = mass/volume.
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Comparison of Densities

Once the density of the unknown substance is calculated, it can be compared to known densities of potential candidates. Isopropyl alcohol has a density of 0.785 g/mL, while toluene has a density of 0.866 g/mL. This comparison helps in identifying the substance by determining which known density is closest to the calculated density.
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Significance of Density in Identification

Density is a characteristic property of substances, meaning it can be used to help identify them. Since different substances have unique densities, measuring the density can provide critical information for distinguishing between similar liquids. In this scenario, the calculated density will indicate whether the substance is more likely to be isopropyl alcohol or toluene based on the comparison.
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Related Practice
Textbook Question

(a) A sample of tetrachloroethylene, a liquid used in dry cleaning that is being phased out because of its potential to cause cancer, has a mass of 40.55 g and a volume of 25.0 mL at 25 °C. What is its density at this temperature? Will tetrachloroethylene float on water? (Materials that are less dense than water will float.)

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Textbook Question

(b) Carbon dioxide (CO2) is a gas at room temperature and pressure. However, carbon dioxide can be put under pressure to become a 'supercritical fluid' that is a much safer dry-cleaning agent than tetrachloroethylene. At a certain pressure, the density of supercritical CO2 is 0.469 g/cm3. What is the mass of a 25.0-mL sample of supercritical CO2 at this pressure?

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Open Question
(a) What is the mass of a silver cube whose edges measure 2.00 cm each at 25 _x001F_C? The density of silver is 10.49 g/cm3 at 25 _x001F_C. (b) The density of aluminum is 2.70 g/cm3 at 25 _x001F_C. What is the weight of the aluminum foil with an area of 0.5 m2 and a thickness of 0.5 mm?
Textbook Question

(b) An experiment requires 45.0 g of ethylene glycol, a liquid whose density is 1.114 g/mL. Rather than weigh the sample on a balance, a chemist chooses to dispense the liquid using a graduated cylinder. What volume of the liquid should he use?

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Textbook Question

(c) Is a graduated cylinder such as that shown in Figure 1.21 likely to afford the accuracy of measurement needed?

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Textbook Question

(d) A cubic piece of metal measures 5.00 cm on each edge. If the metal is nickel, whose density is 8.90 g/cm3, what is the mass of the cube?

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