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Phase Diagrams
13. Liquids, Solids & Intermolecular Forces / Phase Diagrams / Problem 5

At standard pressure, iodine (I2) has a melting point of 113.7°C and a boiling point of 184.3°C. Its liquid phase has a density of 3.96 g/cm3 and its solid phase has a density of 4.93 g/cm3. Its critical temperature and pressure are 546°C and 115 atm while its triple point is at 114°C and 0.12 atm. Starting from a point at 75°C and 5.0 atm the following changes were made:

Step 1: The temperature is increased to 200°C at a constant pressure.
Step 2: The pressure is decreased to 0.500 atm at a constant temperature.
Step 3: The temperature is decreased to 115°C at a constant pressure.
Step 4: The pressure is decreased to 0.050 atm at a constant temperature.

Identify the starting phase and final phases of I2.

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