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Ch.14 - Chemical Kinetics
Chapter 14, Problem 56

The decomposition of XY is second order in XY and has a rate constant of 7.02 * 10^-3 M^-1 s^-1 at a certain temperature. b. How long will it take for the concentration of XY to decrease to 12.5% of its initial concentration when the initial concentration is 0.100 M? When the initial concentration is 0.200 M? c. If the initial concentration of XY is 0.150 M, how long will it take for the concentration to decrease to 0.062 M? d. If the initial concentration of XY is 0.050 M, what is the concentration of XY after 5.0 * 10^1 s? After 5.50 * 10^2 s?

Verified step by step guidance
1
Identify that the reaction is second order, which means the rate law is given by \( \text{Rate} = k[XY]^2 \).
Use the integrated rate law for a second-order reaction: \( \frac{1}{[XY]} = kt + \frac{1}{[XY]_0} \), where \([XY]_0\) is the initial concentration and \([XY]\) is the concentration at time \(t\).
For part b, substitute \([XY]_0 = 0.100 \text{ M}\) and \([XY] = 0.0125 \text{ M}\) into the integrated rate law to solve for \(t\). Repeat the process for \([XY]_0 = 0.200 \text{ M}\).
For part c, substitute \([XY]_0 = 0.150 \text{ M}\) and \([XY] = 0.062 \text{ M}\) into the integrated rate law to solve for \(t\).
For part d, use the integrated rate law with \([XY]_0 = 0.050 \text{ M}\) to find \([XY]\) after \(t = 50 \text{ s}\) and \(t = 550 \text{ s}\).
Related Practice
Textbook Question

This reaction was monitored as a function of time: AB → A + B A plot of 1/[AB] versus time yields a straight line with a slope of +0.55/Ms. c. What is the half-life when the initial concentration is 0.55 M?

Textbook Question

This reaction was monitored as a function of time: AB → A + B A plot of 1/[AB] versus time yields a straight line with a slope of +0.55/Ms.

d. If the initial concentration of AB is 0.250 M, and the reaction mixture initially contains no products, what are the concentrations of A and B after 75 s?

Open Question
a. What is the half-life for the first-order decomposition of SO2Cl2 with a rate constant of 1.42 x 10^-4 s^-1? b. How long will it take for the concentration of SO2Cl2 to decrease to 25% of its initial concentration? c. If the initial concentration of SO2Cl2 is 1.00 M, how long will it take for the concentration to decrease to 0.78 M? d. If the initial concentration of SO2Cl2 is 0.150 M, what is the concentration of SO2Cl2 after 2.00 x 10^2 s? After 5.00 x 10^2 s?
Textbook Question

The decomposition of XY is second order in XY and has a rate constant of 7.02⨉10-3 M-1• s-1 at a certain temperature. a. What is the half-life for this reaction at an initial concentration of 0.100 M?

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Textbook Question

The half-life for the radioactive decay of U-238 is 4.5 billion years and is independent of initial concentration. How long will it take for 10% of the U-238 atoms in a sample of U-238 to decay?

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Textbook Question

The half-life for the radioactive decay of U-238 is 4.5 billion years and is independent of initial concentration. If a sample of U-238 initially contained 1.5⨉1018 atoms when the universe was formed 13.8 billion years ago, how many U-238 atoms does it contain today?

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