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Ch.10 - Gases
Chapter 10, Problem 3

Consider the sample of gas depicted here. What would the drawing look like if the volume and temperature remained constant while you removed enough of the gas to decrease the pressure by a factor of 2? (a) It would contain the same number of molecules. (b) It would contain half as many molecules. (c) It would contain twice as many molecules. (d) There is insufficient data to say.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ideal Gas Law

The Ideal Gas Law relates the pressure, volume, temperature, and number of moles of a gas through the equation PV = nRT. This law helps us understand how changing one variable affects the others, assuming ideal behavior. In this scenario, if the volume and temperature are constant, a decrease in pressure must correspond to a decrease in the number of gas molecules.
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Avogadro's Principle

Avogadro's Principle states that equal volumes of gases, at the same temperature and pressure, contain an equal number of molecules. This principle is crucial for understanding how the number of gas molecules changes with pressure when volume and temperature are held constant. Thus, if the pressure is halved, the number of molecules must also decrease to maintain the relationship defined by this principle.
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Pressure-Volume Relationship

The pressure-volume relationship, often described by Boyle's Law, indicates that for a given amount of gas at constant temperature, the pressure of the gas is inversely proportional to its volume. In this case, since the volume is constant and the pressure is reduced by half, it implies that the number of gas molecules must also decrease, reinforcing the connection between pressure and the quantity of gas present.
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Related Practice
Textbook Question

(c) Calculate the most probable speeds of CO molecules at 300 K.

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Textbook Question

(c) Calculate the most probable speeds of Cl2 molecules at 300 K.

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Textbook Question

You have a sample of gas in a container with a movable piston, such as the one in the drawing. (b) Redraw the container to show what it might look like if the external pressure on the piston is increased from 101.3 kPa to 202.7 kPa while the temperature is kept constant.

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Textbook Question

Imagine that the reaction 2 CO1g2 + O21g2¡2 CO21g2 occurs in a container that has a piston that moves to maintain a constant pressure when the reaction occurs at constant temperature. Which of the following statements describes how the volume of the container changes due to the reaction: (a) the volume increases by 50%, (b) the volume increases by 33%, (c) the volume remains constant, (d) the volume decreases by 33%, (e) the volume decreases by 50%.

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Textbook Question

The apparatus shown here has two gas-filled containers and one empty container, all attached to a hollow horizontal tube. When the valves are opened and the gases are allowed to mix at constant temperature, what is the distribution of atoms in each container?

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Textbook Question

The apparatus shown here has two gas-filled containers and one empty container, all attached to a hollow horizontal tube. Assume that the containers are of equal volume and ignore the volume of the connecting tube. Which gas has the greater partial pressure after the valves are opened?

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