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Ch.6 - Thermochemistry
Chapter 6, Problem 43

The gas in a piston (defined as the system) warms and absorbs 655 J of heat, while performing 344 J of work on the surroundings. What is the change in internal energy for the system?

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Identify the first law of thermodynamics, which states that the change in internal energy (\( \Delta U \)) of a system is equal to the heat added to the system (\( q \)) minus the work done by the system (\( w \)).
Write the formula: \( \Delta U = q - w \).
Substitute the given values into the formula: \( q = 655 \text{ J} \) and \( w = 344 \text{ J} \).
Calculate \( \Delta U \) using the substituted values: \( \Delta U = 655 \text{ J} - 344 \text{ J} \).
Interpret the result: A positive \( \Delta U \) indicates an increase in internal energy, while a negative \( \Delta U \) indicates a decrease.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

First Law of Thermodynamics

The First Law of Thermodynamics states that energy cannot be created or destroyed, only transformed. In a closed system, the change in internal energy is equal to the heat added to the system minus the work done by the system on its surroundings. This principle is fundamental for analyzing energy transfers in thermodynamic processes.
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Internal Energy

Internal energy is the total energy contained within a system, including kinetic and potential energy at the molecular level. It reflects the energy associated with the temperature, phase, and number of particles in the system. Changes in internal energy are crucial for understanding how systems respond to heat and work interactions.
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Work and Heat Transfer

In thermodynamics, work and heat are two primary forms of energy transfer. Work is the energy transferred when a force is applied over a distance, while heat is the energy transferred due to a temperature difference. Understanding how these two forms of energy interact is essential for calculating changes in internal energy and analyzing system behavior.
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Related Practice
Textbook Question

Identify each energy exchange as primarily heat or work and determine whether the sign of ΔE is positive or negative for the system. Identify each energy exchange as primarily heat or work. a. A rolling billiard ball collides with another billiard ball. The first billiard ball (defined as the system) stops rolling after the collision. b. A book falls to the floor. (The book is the system). c. A father pushes his daughter on a swing. (The daughter and the swing are the system). Identify each energy exchange as primarily heat or work.

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Textbook Question

A system releases 622 kJ of heat and does 105 kJ of work on the surroundings. What is the change in internal energy of the system?

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Textbook Question

A system absorbs 196 kJ of heat and the surroundings do 117 kJ of work on the system. What is the change in internal energy of the system?

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Textbook Question

The air in an inflated balloon (defined as the system) warms over a toaster and absorbs 115 J of heat. As it expands, it does 77 kJ of work. What is the change in internal energy for the system?

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Textbook Question

We pack two identical coolers for a picnic, placing 24 12-ounce soft drinks and five pounds of ice in each. However, the drinks that we put into cooler A were refrigerated for several hours before they were packed in the cooler, while the drinks that we put into cooler B were at room temperature. When we open the two coolers three hours later, most of the ice in cooler A is still present, while nearly all of the ice in cooler B has melted. Explain this difference.

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Textbook Question

A kilogram of aluminum metal and a kilogram of water are each warmed to 75 °C and placed in two identical insulated containers. One hour later, the two containers are opened and the temperature of each substance is measured. The aluminum has cooled to 35 °C, while the water has cooled only to 66 °C. Explain this difference.

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