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Ch.14 - Chemical Kinetics

Chapter 14, Problem 96a

Consider the reaction in which HCl adds across the double bond of ethene: HCl + H2C=CH2 → H3C-CH2Cl The following mechanism, with the accompanying energy diagram, has been suggested for this reaction:

Step 1 HCl + H2C=CH2 → H3C=CH2+ + Cl-

Step 2 H3C=CH2+ + Cl- → H3C-CH2Cl

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a. Based on the energy diagram, determine which step is rate limiting.

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