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Ch.23 - Transition Metals and Coordination Chemistry

Chapter 23, Problem 54

As shown in Figure 23.26, the d-d transition of [Ti(H2O)6]³⁺ produces an absorption maximum at a wavelength of about 500 nm .


a. What is the magnitude of ∆ for [Ti(H2O)6]³⁺ in kJ/mol?


b. How would the magnitude of ∆ change if the H2O ligands in [Ti(H2O)6]]³⁺ were placed with NH3 ligands?

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