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Ch.19 - Chemical Thermodynamics
Chapter 19, Problem 4

Predict the signs of ΔH and ΔS for this reaction. Explain your choice.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Enthalpy (ΔH)

Enthalpy (ΔH) is a measure of the total heat content of a system at constant pressure. It indicates whether a reaction is exothermic (releases heat, ΔH < 0) or endothermic (absorbs heat, ΔH > 0). Understanding the enthalpy change helps predict the energy flow during a chemical reaction.
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Entropy (ΔS)

Entropy (ΔS) is a measure of the disorder or randomness in a system. A positive ΔS indicates an increase in disorder, while a negative ΔS suggests a decrease in disorder. The change in entropy is crucial for predicting the spontaneity of a reaction, as reactions tend to favor higher entropy states.
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Gibbs Free Energy (ΔG)

Gibbs Free Energy (ΔG) combines enthalpy and entropy to determine the spontaneity of a reaction at constant temperature and pressure. The relationship ΔG = ΔH - TΔS helps predict whether a reaction will occur spontaneously (ΔG < 0) or not (ΔG > 0). Understanding this concept is essential for analyzing the thermodynamic favorability of reactions.
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