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Ch.14 - Chemical Kinetics

Chapter 14, Problem 92b

Consider three reactions with different values of Ea and ΔE:

Reaction 1. Ea = 20 kJ>mol; ΔE = -60 kJ/mol

Reaction 2. Ea = 10 kJ>mol; ΔE = -20 kJ/mol

Reaction 3. Ea = 40 kJ>mol; ΔE = +15 kJ/mol

(b) Assuming that all three reactions are carried out at the same temperature and that all three have the same frequency factor A, which reaction is the fastest and which is the slowest?

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