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Ch.8 - Periodic Properties of the Elements
Chapter 8, Problem 92

Potassium is a highly reactive metal while argon is an inert gas. Explain this difference based on their electron configurations.

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1
Identify the electron configuration of potassium (K): Potassium has an atomic number of 19, so its electron configuration is 1s^2 2s^2 2p^6 3s^2 3p^6 4s^1.
Identify the electron configuration of argon (Ar): Argon has an atomic number of 18, so its electron configuration is 1s^2 2s^2 2p^6 3s^2 3p^6.
Explain the reactivity of potassium: Potassium has one electron in its outermost shell (4s^1), which it can easily lose to achieve a stable electron configuration similar to the noble gas argon. This makes potassium highly reactive.
Explain the inertness of argon: Argon has a complete outer electron shell (3s^2 3p^6), which makes it stable and unlikely to react with other elements.
Conclude the explanation: The difference in reactivity between potassium and argon is due to their electron configurations, where potassium seeks to lose an electron to achieve stability, while argon already has a stable configuration.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Electron Configuration

Electron configuration describes the distribution of electrons in an atom's orbitals. It is represented using a notation that indicates the energy levels and sublevels occupied by electrons. Understanding electron configuration is crucial for predicting an element's chemical behavior, as it determines how an atom interacts with others during chemical reactions.
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Reactivity of Metals

The reactivity of metals, such as potassium, is largely influenced by their electron configuration, particularly the number of valence electrons. Metals tend to lose electrons to achieve a stable electron configuration, often resembling that of the nearest noble gas. Potassium, with one valence electron, readily loses this electron, making it highly reactive.
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Inert Gases and Stability

Inert gases, like argon, have complete outer electron shells, which makes them chemically stable and unreactive. Their electron configuration follows the octet rule, where having eight electrons in the outer shell leads to minimal tendency to form bonds. This stability is the reason why argon does not readily participate in chemical reactions, contrasting sharply with reactive metals.
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