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Ch.11 - Liquids, Solids & Intermolecular Forces
Chapter 11, Problem 91

Draw a heating curve (such as the one in Figure 11.36) for 1 mole of methanol beginning at 170 K and ending at 350 K. Assume that the values given here are constant over the relevant temperature ranges. Melting point: 176 K, Boiling point: 338 K, ΔH_fus: 2.2 kJ/mol, ΔH_vap: 35.2 kJ/mol, C_s,solid: 105 J/mol·K, C_s,liquid: 81.3 J/mol·K, C_s,gas: 48 J/mol·K.

Verified step by step guidance
1
Identify the different phases and phase transitions of methanol between 170 K and 350 K: solid, liquid, and gas phases, with melting at 176 K and boiling at 338 K.
Calculate the energy required to heat the solid methanol from 170 K to its melting point at 176 K using the formula: \( q = m \cdot C_s,solid \cdot \Delta T \), where \( m \) is the number of moles, \( C_s,solid \) is the specific heat capacity of solid methanol, and \( \Delta T \) is the temperature change.
Determine the energy needed for the phase transition from solid to liquid at the melting point using the formula: \( q = m \cdot \Delta H_{fus} \), where \( \Delta H_{fus} \) is the enthalpy of fusion.
Calculate the energy required to heat the liquid methanol from 176 K to its boiling point at 338 K using the formula: \( q = m \cdot C_s,liquid \cdot \Delta T \), where \( C_s,liquid \) is the specific heat capacity of liquid methanol.
Determine the energy needed for the phase transition from liquid to gas at the boiling point using the formula: \( q = m \cdot \Delta H_{vap} \), where \( \Delta H_{vap} \) is the enthalpy of vaporization.
Related Practice
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Four ice cubes at exactly 0 °C with a total mass of 53.5 g are combined with 115 g of water at 75 °C in an insulated container. If no heat is lost to the surroundings, what is the final temperature of the mixture?
Textbook Question

A sample of steam with a mass of 0.552 g and at a temperature of 100 °C condenses into an insulated container holding 4.25 g of water at 5.0 °C. Assuming that no heat is lost to the surroundings, what is the final temperature of the mixture?

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Open Question
Draw a heating curve (such as the one in Figure 11.36) for 1 mol of benzene beginning at 0 °C and ending at 100 °C. Assume that the values given here are constant over the relevant temperature ranges: Melting point 5.4 °C, Boiling point 80.1 °C, ΔHfus 9.9 kJ/mol, ΔHvap 30.7 kJ/mol, Cs,solid 118 J/mol⋅K, Cs,liquid 135 J/mol⋅K, Cs,gas 104 J/mol⋅K.
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Textbook Question

A sealed flask contains 0.55 g of water at 28 °C. The vapor pressure of water at this temperature is 28.35 mmHg. What is the minimum volume of the flask in order that no liquid water be present in the flask?

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