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Ch.1 - Matter, Measurement & Problem Solving

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Chapter 14, Problem 77c

Consider this three-step mechanism for a reaction:
Cl₂ (g) k₁⇌k₂ 2 Cl (g) Fast
Cl (g) + CHCl₃ (g) →k₃ HCl (g) + CCl₃ (g) Slow
Cl (g) + CCl₃ (g) →k₄ CCl₄ (g) Fast
c. What is the predicted rate law?

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Chapter 14, Problem 77c

Consider this three-step mechanism for a reaction:Cl2 (g) k1⇌k2 2 Cl (g) FastCl (g) + CHCl3 (g) →k3 HCl (g) + CCl3 (g) SlowCl (g) + CCl3 (g) →k4 CCl4 (g) Fastc. What is the predicted rate law?

Consider this three-step mechanism for a reaction:
Cl₂ (g) k₁⇌k₂ 2 Cl (g) Fast
Cl (g) + CHCl₃ (g) →k₃ HCl (g) + CCl₃ (g) Slow
Cl (g) + CCl₃ (g) →k₄ CCl₄ (g) Fast
c. What is the predicted rate law?