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Ch.14 - Chemical Kinetics

Chapter 14, Problem 95d

Consider this energy diagram:

d. Is the overall reaction endothermic or exothermic?

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Welcome back everyone in this example, we need to determine whether our reaction is endo thermic or exo thermic based on our energy diagram. So looking at our energy diagram, we can see that energy which is recorded on our y. Axis of our products, is much lower compared to the energy of our reactant, which is at a much higher energy. So because we can say that the energy of our reactant is greater than the energy of our products, we can say that therefore there is less energy needed to break the bonds of our reactant then is released when the bonds of our products are formed. And so what we're saying is that more energy is actually being released in this reaction. And so we would say therefore we have an exo thermic reaction. And so our final answer is going to be that this reaction is X. A. Thermic based on the diagram. So this is our final answer. If you have any questions, please leave them down below. And I will see everyone in the next practice video.
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Dinitrogen pentoxide decomposes in the gas phase to form nitrogen dioxide and oxygen gas. The reaction is first order in dinitrogen pentoxide and has a half-life of 2.81 h at 25 °C. If a 1.5-L reaction vessel initially contains 745 torr of N2O5 at 25 °C, what partial pressure of O2 is present in the vessel after 215 minutes?

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Textbook Question

Iodine atoms combine to form I2 in liquid hexane solvent with a rate constant of 1.5⨉1010 L/mols. The reaction is second order in I. Since the reaction occurs so quickly, the only way to study the reaction is to create iodine atoms almost instantaneously, usually by photochemical decomposition of I2. Suppose a flash of light creates an initial [I] concentration of 0.0100 M. How long will it take for 95% of the newly created iodine atoms to recombine to form I2?

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Textbook Question

Consider this energy diagram:

a. How many elementary steps are involved in this reaction?

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Textbook Question

Consider the reaction in which HCl adds across the double bond of ethene: HCl + H2C=CH2 → H3C-CH2Cl The following mechanism, with the accompanying energy diagram, has been suggested for this reaction:

Step 1 HCl + H2C=CH2 → H3C=CH2+ + Cl-

Step 2 H3C=CH2+ + Cl- → H3C-CH2Cl

a. Based on the energy diagram, determine which step is rate limiting.

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Textbook Question

Consider the reaction in which HCl adds across the double bond of ethene: HCl + H2C=CH2 → H3C-CH2Cl The following mechanism, with the accompanying energy diagram, has been suggested for this reaction:

Step 1 HCl + H2C=CH2 → H3C=CH2+ + Cl-

Step 2 H3C=CH2+ + Cl- → H3C-CH2Cl

b. What is the expected order of the reaction based on the proposed mechanism?

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Textbook Question

The desorption (leaving of the surface) of a single molecular layer of n-butane from a single crystal of aluminum oxide is found to be first order with a rate constant of 0.128/s at 150 K. a. What is the half-life of the desorption reaction?-

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