Chapter 7, Problem 33c
Consider S, Cl, and K and their most common ions.(c) Explain any differences in the orders of the atomic and ionic sizes.
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Consider the isoelectronic ions F- and Na+. (b) Using Equation 7.1 and assuming that core electrons contribute 1.00 and valence electrons contribute 0.00 to the screening constant, S, calculate Zeff for the 2p electrons in both ions.
Consider the isoelectronic ions F- and Na+. (d) For isoelectronic ions, how are effective nuclear charge and ionic radius related?
Consider S, Cl, and K and their most common ions. (a) List the atoms in order of increasing size.
Provide a brief explanation for each of the following.
K+ is larger than Na+.
In the ionic compounds LiF, NaCl, KBr, and RbI, the measured cation–anion distances are 201 pm (Li–F), 282 pm (Na–Cl), 330 pm (K–Br), and 367 pm (Rb–I), respectively. (b) Calculate the difference between the experimentally measured ion–ion distances and the ones predicted from Figure 7.8.