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Ch.6 - Thermochemistry

Chapter 6, Problem 77b

For each generic reaction, determine the value of ΔH2 in terms of ΔH1. b. A + 1/2 B → C ΔH1 2 A + B → 2 C ΔH2 = ?

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everyone in this example we need to express our second entropy in terms of our first entropy. So looking at our second entropy expression, we have four moles of our reactant C, which produces six moles of our product B and two moles of our product A. However in our first entropy expression we have a one mole of A reacting with three moles of B to produce two moles of C. So it looks like our reaction here has flipped. And so in order to write our first entropy in terms of our second entropy we would want to flip the sign of our entropy of our first expression here because we want to go ahead and make our B and A. As products as they are expressed in our second entropy expression here. And so that would flip our reaction so that C. Is a reactant and B and A would be products. We also want to recognize that our moles of B and A need to be doubled and so we would go ahead and multiply this expression by two and so to express our second entropy. In terms of our first entropy we would say that our second entropy is going to equal -2 times our first entropy expression. And so this would be our final answer to complete this example. So I hope that everything I reviewed was clear. If you have any questions, please leave them down below and I will see everyone in the next practice video
Related Practice
Textbook Question

Zinc metal reacts with hydrochloric acid according to the balanced equation: Zn(s) + 2 HCl(aq)¡ZnCl2(aq) + H2( g) When 0.103 g of Zn(s) is combined with enough HCl to make 50.0 mL of solution in a coffee-cup calorimeter, all of the zinc reacts, raising the temperature of the solution from 22.5 °C to 23.7 °C. Find ΔHrxn for this reaction as written. (Use 1.0 g>mL for the density of the solution and 4.18 J>g # °C as the specific heat capacity.)

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Textbook Question

Instant cold packs used to ice athletic injuries on the field contain ammonium nitrate and water separated by a thin plastic divider. When the divider is broken, the ammonium nitrate dissolves according to the endothermic reaction: NH4NO3(s)¡NH4 + (aq) + NO3- (aq) In order to measure the enthalpy change for this reaction, 1.25 g of NH4NO3 is dissolved in enough water to make 25.0 mL of solution. The initial temperature is 25.8 °C and the final temperature (after the solid dissolves) is 21.9 °C. Calculate the change in enthalpy for the reaction in kJ. (Use 1.0 g > mL as the density of the solution and 4.18 J>g # °C as the specific heat capacity.)

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Textbook Question

For each generic reaction, determine the value of ΔH2 in terms of ΔH1. a. A + B → 2 C ΔH1 2 C→ A + B ΔH2 = ?

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Textbook Question

For each generic reaction, determine the value of ΔH2 in terms of ΔH1. c. A → B + 2 C ΔH1 1/2 B + C → 1/2 A ΔH2 = ?

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Textbook Question

Consider the generic reaction: A + 2 B¡C + 3 D ΔH = 155 kJ Determine the value of ΔH for each related reaction. a. 3 A + 6 B¡3 C + 9 D b. C + 3 D¡A + 2 B c. 12 C + 32 D¡12 A + B

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Textbook Question

Calculate ΔHrxn for the reaction: Fe2O3(s) + 3 CO( g)¡2 Fe(s) + 3 CO2( g) Use the following reactions and given ΔH's: 2 Fe(s) + 32 O2( g)¡Fe2O3(s) ΔH = -824.2 kJ CO( g) + 12 O2( g)¡CO2( g) ΔH = -282.7 kJ

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