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Ch.11 - Liquids, Solids & Intermolecular Forces
Chapter 11, Problem 82

How is the density of solid water compared to that of liquid water atypical among substances, and why is this significant?

Verified step by step guidance
1
Identify the typical behavior of substances: In most substances, the solid phase is denser than the liquid phase because the molecules are packed more closely together in the solid state.
Describe the structure of solid water (ice): Ice has a unique crystalline structure where water molecules are arranged in a hexagonal lattice, which is maintained by hydrogen bonds.
Explain the effect of the hexagonal lattice: This structure causes the molecules in ice to be spaced further apart than in liquid water, resulting in a lower density for ice compared to liquid water.
Discuss the significance of this property: Because ice is less dense than liquid water, it floats. This is crucial for aquatic life, as it insulates the water below and provides a habitat for organisms.
Conclude with the broader implications: The lower density of ice compared to liquid water is an anomaly that has significant environmental and ecological impacts, influencing climate and life on Earth.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Density and Phase Changes

Density is defined as mass per unit volume and typically increases as substances transition from a liquid to a solid state. However, most substances are denser in their solid form than in their liquid form. This is due to the arrangement of molecules; in solids, they are usually packed more closely together. Understanding this concept is crucial for analyzing the behavior of water as it freezes.
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Hydrogen Bonding in Water

Water molecules exhibit strong hydrogen bonding, which significantly influences their physical properties. When water freezes, these bonds cause the molecules to arrange in a hexagonal lattice structure, leading to an increase in volume and a decrease in density. This unique behavior is essential for understanding why ice floats on liquid water, which is atypical compared to most other substances.
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Ecological Significance of Ice Density

The lower density of ice compared to liquid water has profound ecological implications. It allows ice to float on water bodies, creating an insulating layer that protects aquatic life during cold seasons. This phenomenon is vital for maintaining ecosystems, as it influences temperature regulation and habitat availability for various organisms.
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