Chapter 8, Problem 107a
Carbon monoxide is produced by incomplete combustion of fossil fuels. (a) Give the electron configuration for the valence molecular orbitals of CO. The orbitals have the same energy order as those of the N2 molecule.
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At high temperatures, sulfur vapor is predominantly in the form of S2(g) molecules. (a) Assuming that the molecular orbitals for third-row diatomic molecules are analogous to those for second-row molecules, construct an MO diagram for the valence orbitals of S2(g).
At high temperatures, sulfur vapor is predominantly in the form of S2(g) molecules. (d) When two electrons are added to S2, the disulfide ion S22- is formed. Is the bond length in S22- likely to be shorter or longer than the bond length in S2? Explain.
Carbon monoxide is produced by incomplete combustion of fossil fuels. (b) Do you expect CO to be paramagnetic or diamagnetic?
Carbon monoxide is produced by incomplete combustion of fossil fuels. (c) What is the bond order of CO? Does this match the bond order predicted by the electron-dot structure?