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Ch.18 - Free Energy and Thermodynamics
Chapter 18, Problem 69

Consider the sublimation of iodine at 25.0 °C: I2(s) → I2(g). a. Find ΔG°rxn at 25.0 °C.

Verified step by step guidance
1
Identify the relevant thermodynamic equation: \( \Delta G^\circ_{\text{rxn}} = \Delta H^\circ - T\Delta S^\circ \).
Look up the standard enthalpy change (\( \Delta H^\circ \)) and the standard entropy change (\( \Delta S^\circ \)) for the sublimation of iodine from a reliable source, such as a chemistry textbook or database.
Convert the temperature from Celsius to Kelvin by adding 273.15 to the Celsius temperature: \( T = 25.0 + 273.15 \).
Substitute the values of \( \Delta H^\circ \), \( T \) (in Kelvin), and \( \Delta S^\circ \) into the equation \( \Delta G^\circ_{\text{rxn}} = \Delta H^\circ - T\Delta S^\circ \).
Perform the calculation to find \( \Delta G^\circ_{\text{rxn}} \), ensuring that the units are consistent (e.g., convert \( \Delta S^\circ \) from J/mol·K to kJ/mol·K if necessary).