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Ch.9 - Chemical Bonding I: The Lewis Model
Chapter 9, Problem 88

Does each compound contain both ionic and covalent bonds? Write ionic Lewis structures for each of them, including the covalent structure for the ion in brackets. Write resonance structures if necessary for the following: b. NH4Cl, d. Sr(CN)2, a. RbIO2, c. KOH.

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<b>Step 1:</b> Identify the types of bonds present in each compound. Ionic bonds typically form between metals and nonmetals, while covalent bonds form between nonmetals. For each compound, determine which parts are ionic and which are covalent.
<b>Step 2:</b> For NH4Cl, recognize that NH4+ is a polyatomic ion with covalent bonds between nitrogen and hydrogen atoms. The compound also contains an ionic bond between NH4+ and Cl-. Draw the Lewis structure for NH4+ showing the covalent bonds, and indicate the ionic bond with Cl-.
<b>Step 3:</b> For Sr(CN)2, identify that Sr2+ forms ionic bonds with the CN- ions. Within each CN- ion, there is a covalent bond between carbon and nitrogen. Draw the Lewis structure for CN- showing the covalent bond, and indicate the ionic bond with Sr2+.
<b>Step 4:</b> For RbIO2, recognize that Rb+ forms an ionic bond with the IO2- ion. Within IO2-, there are covalent bonds between iodine and oxygen atoms. Draw the Lewis structure for IO2- showing the covalent bonds, and indicate the ionic bond with Rb+.
<b>Step 5:</b> For KOH, identify that K+ forms an ionic bond with OH-. Within OH-, there is a covalent bond between oxygen and hydrogen. Draw the Lewis structure for OH- showing the covalent bond, and indicate the ionic bond with K+.
Related Practice
Textbook Question

In the Chemistry and the Environment box on free radicals in this chapter, we discussed the importance of the hydroxyl radical in reacting with and eliminating many atmospheric pollutants. However, the hydroxyl radical does not clean up everything. For example, chlorofluorocarbons—which destroy stratospheric ozone—are not attacked by the hydroxyl radical. Consider the hypothetical reaction by which the hydroxyl radical might react with a chlorofluorocarbon: OH(g) + CF2Cl2(g) → HOF(g) + CFCl2(g) Use bond energies to explain why this reaction is improbable. (The C–F bond energy is 552 kJ/mol.)

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Textbook Question

Write an appropriate Lewis structure for each compound. Make certain to distinguish between ionic and molecular compounds. b. ClF5

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Textbook Question

Each compound contains both ionic and covalent bonds. Write ionic Lewis structures for each, including the covalent structure for the ion in brackets. Write resonance structures if necessary. a. BaCO3

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Textbook Question

Carbon ring structures are common in organic chemistry. Draw a Lewis structure for each carbon ring structure, including any necessary resonance structures. a. C4H8 b. C4H4 c. C6H12 d. C6H6

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Textbook Question

Amino acids are the building blocks of proteins. The simplest amino acid is glycine (H2NCH2COOH). Draw a Lewis structure for glycine. (Hint: The central atoms in the skeletal structure are nitrogen and the two carbon atoms. Each oxygen atom is bonded directly to the right-most carbon atom.)

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Textbook Question

Formic acid is responsible for the sting of ant bites. By mass, formic acid is 26.10% C, 4.38% H, and 69.52% O. The molar mass of formic acid is 46.02 g/mol. Determine the molecular formula of formic acid and draw its Lewis structure.

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