The water supply for a midwestern city contains the following impurities: coarse sand, finely divided particulates, nitrate ions, trihalomethanes, dissolved phosphorus in the form of phosphates, potentially harmful bacterial strains, dissolved organic substances. Which of the following processes or agents, if any, is effective in removing each of these impurities: coarse sand filtration, activated carbon filtration, aeration, ozonization, precipitation with aluminum hydroxide?
Ch.18 - Chemistry of the Environment
Chapter 18, Problem 82c
The concentration of H2O in the stratosphere is about 5 ppm. It undergoes photodissociation according to: H2O(g) → H(g) + OH(g)
(c) The hydroxyl radical, OH, can react with ozone, giving the following reactions:
OH(g) + O3(g) → HO2(g) + O2(g)
HO2(g) + O(g) → OH(g) + O2(g)
What overall reaction results from these two elementary reactions? What is the catalyst in the overall reaction? Explain.

1
Identify the two given elementary reactions: 1) OH(g) + O3(g) → HO2(g) + O2(g) and 2) HO2(g) + O(g) → OH(g) + O2(g).
To find the overall reaction, add the two elementary reactions together. This involves adding the reactants and products of both reactions.
Cancel out any species that appear on both sides of the resulting equation. In this case, OH(g) appears as both a reactant and a product, so it can be canceled out.
After canceling out the common species, write down the remaining reactants and products to form the overall reaction.
Identify the catalyst in the reaction. A catalyst is a substance that is present at the start and end of the reaction without being consumed. In this case, OH(g) is the catalyst as it is regenerated in the process.

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