Chapter 17, Problem 14c
Consider the equilibrium B1aq2 + H2O1l2 Δ HB+1aq2 + OH-1aq2. Suppose that a salt of HB+1aq2 is added to a solution of B1aq2 at equilibrium. (c) Will the pH of the solution increase, decrease, or stay the same?
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Ca1OH22 has a Ksp of 6.5 * 10-6. (b) If 50 mL of the solution from part (a) is added to each of the beakers shown here, in which beakers, if any, will a precipitate form? In those cases where a precipitate forms, what is its identity? [Section 17.6]
Three cations, Ni2+ , Cu2+ , and Ag+, are separated using two different precipitating agents. Based on Figure 17.23, what two precipitating agents could be used? Using these agents, indicate which of the cations is A, which is B, and which is C.[Section 17.7]
Which of these statements about the common-ion effect is most correct? (a) The solubility of a salt MA is decreased in a solution that already contains either M+ or A-. (b) Common ions alter the equilibrium constant for the reaction of an ionic solid with water. (c) The common-ion effect does not apply to unusual ions like SO32 - . (d) The solubility of a salt MA is affected equally by the addition of either A- or a noncommon ion.
(a) Calculate the percent ionization of 0.0075 M butanoic acid 1Ka = 1.5 * 10-52.
(b) Calculate the percent ionization of 0.0075 M butanoic acid in a solution containing 0.085 M sodium butanoate.
(a) Calculate the percent ionization of 0.125 M lactic acid 1Ka = 1.4 * 10-42.