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Ch.20 - Electrochemistry
Chapter 20, Problem 73b

During a period of discharge of a lead–acid battery, 402 g of Pb from the anode is converted into PbSO4(s). (b) How many coulombs of electrical charge are transferred from Pb to PbO2?

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Identify the chemical reaction occurring in the lead-acid battery during discharge. The anode reaction is: \[ \text{Pb} + \text{SO}_4^{2-} \rightarrow \text{PbSO}_4 + 2e^- \].
Determine the moles of Pb involved in the reaction. Use the molar mass of Pb (207.2 g/mol) to convert the given mass of Pb (402 g) to moles: \[ \text{moles of Pb} = \frac{402 \text{ g}}{207.2 \text{ g/mol}} \].
Calculate the total number of moles of electrons transferred. Since each mole of Pb produces 2 moles of electrons, multiply the moles of Pb by 2.
Use Faraday's constant to convert moles of electrons to coulombs. Faraday's constant is approximately 96485 C/mol. Multiply the moles of electrons by Faraday's constant to find the total charge in coulombs.
Summarize the process: The total charge transferred is the product of the moles of electrons and Faraday's constant, which gives the number of coulombs of electrical charge transferred from Pb to PbO2.

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A voltaic cell is constructed with two Zn²⁺/Zn electrodes. The two half-cells have [Zn²⁺] = 1.8 M and [Zn²⁺] = 1.00 × 10⁻² M, respectively. (a) Which electrode is the anode of the cell? (b) What is the standard emf of the cell? (c) What is the cell emf for the concentrations given? (d) For each electrode, predict whether [Zn²⁺] will increase, decrease, or stay the same as the cell operates.
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During a period of discharge of a lead–acid battery, 402 g of Pb from the anode is converted into PbSO4(s). (a) What mass of PbO2(s) is reduced at the cathode during this same period?

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