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Ch.8 - Periodic Properties of the Elements
Chapter 8, Problem 91

Bromine is a highly reactive liquid while krypton is an inert gas. Explain this difference based on their electron configurations.

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Identify the electron configuration of bromine: Bromine (Br) has an atomic number of 35. Its electron configuration is [Ar] 3d^10 4s^2 4p^5.
Identify the electron configuration of krypton: Krypton (Kr) has an atomic number of 36. Its electron configuration is [Ar] 3d^10 4s^2 4p^6.
Explain the reactivity of bromine: Bromine has 7 electrons in its outermost p orbital (4p^5), which means it needs one more electron to achieve a stable, full octet configuration. This makes bromine highly reactive as it tends to gain an electron to achieve stability.
Explain the inertness of krypton: Krypton has a complete outer shell with 8 electrons in its outermost p orbital (4p^6), achieving a stable noble gas configuration. This full octet makes krypton chemically inert, as it does not need to gain or lose electrons.
Conclude the difference: The difference in reactivity between bromine and krypton is due to their electron configurations. Bromine is reactive because it seeks to complete its octet, while krypton is inert because it already has a complete octet.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Electron Configuration

Electron configuration describes the distribution of electrons in an atom's orbitals. It is represented using a notation that indicates the energy levels and sublevels occupied by electrons. Understanding electron configuration is crucial for predicting an element's chemical behavior, as it determines how an atom interacts with others.
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Reactivity of Elements

The reactivity of elements is largely influenced by their electron configurations, particularly the presence of unpaired electrons in the outermost shell. Elements with incomplete outer shells, like bromine, tend to be more reactive as they seek to achieve stability by gaining, losing, or sharing electrons. In contrast, elements with full outer shells, like krypton, are generally inert and do not readily participate in chemical reactions.
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Noble Gases vs. Halogens

Noble gases, such as krypton, have complete valence electron shells, making them stable and unreactive. In contrast, halogens like bromine have seven valence electrons and require only one more to achieve a full shell, which makes them highly reactive. This fundamental difference in electron configuration explains the contrasting chemical behaviors of these two groups of elements.
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