Draw the hydration shells that form around a potassium ion and a chloride ion when potassium chloride (KCl) dissolves in water. Label the positive, negative, and partial charges on the atoms.
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Begin by understanding that when potassium chloride (KCl) dissolves in water, it dissociates into potassium ions (K⁺) and chloride ions (Cl⁻). These ions interact with water molecules, forming hydration shells.
Identify the structure of a water molecule, which consists of two hydrogen atoms and one oxygen atom. The oxygen atom has a partial negative charge (δ⁻), while the hydrogen atoms have partial positive charges (δ⁺).
For the potassium ion (K⁺), draw several water molecules around it. The oxygen atoms of the water molecules, which have partial negative charges, will orient themselves towards the positively charged potassium ion.
For the chloride ion (Cl⁻), draw several water molecules around it. The hydrogen atoms of the water molecules, which have partial positive charges, will orient themselves towards the negatively charged chloride ion.
Label the charges: Indicate the positive charge on the potassium ion (K⁺), the negative charge on the chloride ion (Cl⁻), and the partial charges on the water molecules (δ⁺ on hydrogen and δ⁻ on oxygen). This labeling helps visualize the electrostatic interactions forming the hydration shells.
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Hydration Shells
Hydration shells are layers of water molecules that surround ions when they dissolve in water. The polar nature of water allows it to interact with charged particles, forming a shell where the water's partial charges align with the ion's charge, stabilizing the ion in solution.
Water is a polar molecule, meaning it has a partial positive charge on the hydrogen atoms and a partial negative charge on the oxygen atom. This polarity enables water to interact with and stabilize ions in solution, as the opposite charges attract, forming hydration shells around dissolved ions.
When ionic compounds like potassium chloride dissolve in water, the ions separate and become surrounded by water molecules. This process involves the breaking of ionic bonds and the formation of new interactions between the ions and water, facilitated by the polar nature of water molecules.