Physical Chemistry: Thermodynamics, Statistical Mechanics, and Kinetics, 1st edition

Published by Pearson (January 4, 2013) © 2014

  • Andrew Cooksy

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Andrew Cooksy’s clear teaching voice help students connect immediately with the subject matter while defusing some of their initial trepidation about physical chemistry. Through lively narrative and meticulous explanations of mathematical derivations, Physical Chemistry: Thermodynamics, Statistical Mechanics, and Kineticsengages students while fostering a sincere appreciation for the interrelationship between the theoretical and mathematical reasoning that underlies the study of physical chemistry. The author’s engaging presentation style and careful explanations make even the most sophisticated concepts and mathematical details clear and comprehensible.  

FLEXIBLE ORGANIZATION ACCOMMODATES THE CONTENT NEEDS AND TEACHING STYLES OF EACH SEMESTER/QUARTER SEQUENCE.

Separation of Quantum Chemistry and Thermodynamics into distinct volumes provides the utmost in flexibility, allowing instructors to lead with their choice of Quantum-first or Thermo-first coverage.

  • For students in need of a review at the start of the term/quarter, Chapter A: “Tools of Math and Physics” summarizes the prerequisite mathematics and physics assumed by the rest of the text. While the text reminds the student of specific equations from basic math and physics as needed, Chapter A underscores the fundamental nature of the course material by presenting at the outset the essential math and physics principles from which we construct chemical theory.
  • Reflective of popular lecture strategies, chapter opening and closing features ground each topic within the larger framework of physical chemistry and help students stay oriented as they deepen their understanding.
    • Opening features including a “Visual Roadmap” and “Context: Where Are We Now” show  readers where they are within the text and relative to other physical chemistry topics.
    • “Goal: Why Are We Here?” and “Learning Objectives” features prepare students for the work ahead and outline the skills students should expect to acquire from their study of the chapter.
    • The concluding “Where Do We Go From Here” section at the end of each chapter reinforces student orientation and illuminates the intrinsic connection between concepts..

COOKSY’S PRECISE EXPOSITION AND UNIQUE FEATURES STRENGTHEN STUDENTS’ UNDERSTANDING AND ABILITIES IN QUANTITATIVE AND QUALITATIVE REASONING.

Derivations demystified: Derivations are made transparent and comprehensible to students without sacrifice of mathematical rigor. Colored annotations provide crucial help to students by explaining important steps in key derivations. Step-by-step derivations are also supported by detailed marginal notes explaining each step enabling students to retrace the math at a leisurely pace and freeing up instructor time in lecture.

  • Thoughtful color-coding in key equations makes it easier for students to follow the development of complex derivations as well as recognize common mathematical elements that appear in the representation of different physical situations.

    Summaries spell out the essential results of difficult derivations, making it easier to accommodate the needs of different courses, the preferences of different instructors, and the study and review habits of different students.
  • In-chapter Sample Calculations focus on inputting values into important equations, to convey a sense of reasonable numerical values of derived parameters, expose students to essential unit conversions, and reinforce a basic understanding of the related principles.
  • Simple Word Problems and Examples expose students to connections between a Key Equation and a specific application from chemistry, biochemistry, or chemical engineering. .
  • End-of-chapter problems test the student’s grasp of chapter material, from a superficial awareness to progressively deeper levels of understanding, often requiring the consolidation of material from preceding chapters. The problems are divided into “Discussion Problems” that require little or no math, and “Quantitative Questions” that test the student’s ability to obtain specific results identifying the relevant concepts then manipulating the corresponding equations and approximations of physical chemistry.  Exercises draw primarily from fundamental molecular physics and physical organic chemistry, but also incorporate biochemical and chemical engineering applications.

ACTIVE RESEARCH, ACTUAL TOOLS, AND TECHNIQUES: LEARNING ABOUT THE INSTRUMENTS AND METHODS OF MODERN PHYSICAL CHEMISTRY, AND MEETING RESEARCHERS AT WORK TODAY, STUDENTS GAIN AN APPRECIATION FOR THE PRACTICAL APPLICATIONS OF THIS SCIENCE TO MANY FIELDS.

  • Full-page Tools of the Trade sections highlight the design and operation of commonly used experimental apparatuses and how they relate to the principles discussed in the chapter.
  • Biosketches in each chapter present a brief description and profile of a contemporary scientist or engineer and their current research relating to Physical Chemistry.  Subjects reflect a diverse range of applications, locations, and stages of achievement, demonstrating the wealth of opportunity in chemistry, as well as the relevance of physical chemistry to all other subdisciplines in the molecular sciences.
  • An open access, online solutions manual includes step-by-step worked solutions–written by the author-- for all end-of-chapter problems. Unlike most solutions manuals, these unique solution sets emphasize qualitative results at the conclusion of many problems to help students move beyond the math to a deeper understanding of the concepts. Guides to solving more complicated problems with symbolic math software such as Maple and Mathematica are also provided.

Physical Chemistry at the Macroscopic Scale:

Statistical Mechanics, Thermodynamics, and Kinetics

 

A Introduction: Tools from Math and Physics

A.1 Mathematics

A.2 Classical Physics

 

I Extrapolation to Macroscopic Systems

1 Introduction to Statistical Mechanics: Building Up to the Bulk

1.1 Properties of the Microscopic World

1.2 Bulk properties

1.3 Entropy

1.4 The ideal gas and translational states

1.5 The ideal gas law

Problems

 

2 Partitioning the Energy

2.1 Separation of Degrees of Freedom

2.2 The equipartition principle

2.3 Vibrational and rotational partition functions

2.4 The Translational Density of States

2.5 The translational partition function

2.6 Temperature and the Maxwell-Boltzmann distribution

Problems

 

3 Statistical Mechanics and Molecular Interactions

3.1 Extrapolation to many molecules

3.2 Pressure of a non-ideal fluid

3.3 Averaging the dipole-dipole potential

3.4 Bose-Einstein and Fermi-Dirac statistics

 

4 Mass Transport

4.1 Statistics of molecular collisions

4.2 Transport without external forces

4.3 Transport with external forces

Problems

 

5 Energy transport

5.1 Conduction, convection, and radiation

5.2 Blackbody radiation

5.3 Spectroscopic intensities

5.4 Laser dynamics

5.5 Spectroscopic linewidths

5.6 Conclusion to Part IV: E, U, Ndof , S

Problems

 

II Non-Reactive Macroscopic Systems

6 Introduction to Thermodynamics

6.1 The first law of thermodynamics

6.2 Approximations and assumptions

6.3 Mathematical tools

6.4 Computer simulations

Problems

 

7 Energy and Enthalpy

7.1 Heat capacities

7.2 Expansion of gases

Problems

 

8 Entropy

8.1 Entropy of an ideal gas

8.2 The second law of thermodynamics

8.3 The third law of thermodynamics

8.4 Ideal mixing

Problems

 

9 Phase Transitions and Phase Equilibrium

9.1 Phase transitions

9.2 Thermodynamics of phase transitions

9.3 Chemical potentials

9.4 Statistical mechanics of vaporization

9.5 Phase diagrams

Problems

 

10 Solutions

10.1 The standard states

10.2 Statistical mechanics of solutions

10.3 Thermodynamics of solutions

10.4 Ionic solutions

10.5 Applications of the activity

10.6 Conclusion to Part V: E, U, Ndof , S

Problems

 

III Reactive Systems

11 Chemical Thermodynamics

11.1 Introduction to chemical reactions

11.2 Enthalpies of reaction

11.3 Spontaneous chemical reactions

11.4 Chemical equilibrium

Problems

 

12 Elementary Reactions

12.1 Reaction rates

12.2 Simple collision theory

12.3 Transition state theory

12.4 Diffusion-limited rate constants

12.5 Rate laws for elementary reactions

Problems

 

13 Multi-step Reactions

13.1 Elements of multi-step reactions

13.2 Approximations in kinetics

13.3 Chain reactions

Problems

 

14 Reaction Networks

14.1 Atmospheric chemistry

14.2 Combustion chemistry

14.3 Molecular astrophysics

14.4 Enzyme catalysis

14.5 Conclusion to the text

 

 

Andrew Cooksy is a chemistry professor at San Diego State University, where he teaches courses in physical and general chemistry and carries out research on the spectroscopy, kinetics, and computational chemistry of reactive intermediates in combustion and interstellar processes. He attended the Washington, D.C. public schools before receiving his undergraduate degree in chemistry and physics from Harvard College and his Ph.D. in chemistry from the University of California at Berkeley.

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