Guided course 06:General properties of strong oxidative cleavage.Johnny Betancourt1535views13rank9comments
Textbook Questiona. What alkene would give only a ketone with three carbons as a product of oxidative cleavage?367views
Textbook QuestionPredict the major products of the following reactions. b. (Z)-3-methyloct-3-ene + warm, concentrated KMnO4525views
Textbook QuestionPredict the major products of the following reactions, and give the structures of any intermediates. Include stereochemistry where appropriate. k. 656views
Textbook QuestionThe sex attractant of the housefly has the formula C23H46. When treated with warm potassium permanganate, this pheromone gives two products: CH3(CH2)12COOH and CH3(CH2)7COOH. Suggest a structure for this sex attractant. Explain which part of the structure is uncertain.508views
Textbook QuestionShow how you would accomplish the following syntheses efficiently (you may use any necessary reagents). (b) hex-3-ene --> propanoic acid438views
Textbook QuestionPredict the products obtained when d-galactose reacts with each reagent. (k) excess HIO4341views
Textbook QuestionLimonene is one of the compounds that give lemons their tangy odor. Show the structures of the products expected when limonene reacts with an excess of each of these reagents. <IMAGE>e. hot, concentrated potassium permanganate307views
Textbook QuestionPredict the major products of the following reactions.e. 1-ethylcycloheptene + warm, concentrated KMnO4Problem-Solving Hint: Three reagents oxidize the pi bond of an alkene but leave the sigma bond intact: (a) cold, dilute KMnO4; (b) OsO4-H2O2; and (c) RCO3H epoxidation.Two reagents break the double bond entirely, giving carbonyl groups: (a) warm, concentrated KMnO4 and (b) O3 followed by (CH3)2S.295views
Textbook QuestionUnknown X, C5H9Br does not react with bromine or with dilute KMnO4. Upon treatment with potassium tert-butoxide, X gives only one product, Y,C5H8. Unlike X, Y decolorizes bromine and changes KMnO4 from purple to brown. Catalytic hydrogenation of Y gives methylcyclobutane. Ozonolysis–reduction of Y gives dialdehyde Z, C5H8O2. Propose consistent structures for X, Y, and Z. Is there any aspect of the structure of X that is still unknown?232views
Textbook QuestionAn unknown compound decolorizes bromine in carbon tetrachloride, and it undergoes catalytic reduction to give decalin. When treated with warm, concentrated potassium permanganate, this compound gives cis-cyclohexane-1,2-dicarboxylic acid and oxalic acid. Propose a structure for the unknown compound.<IMAGE>295views
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