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Hammond Postulate

6. Thermodynamics and Kinetics / Hammond Postulate / Problem 2

Which of the given electrophilic addition reactions would you expect to be more selective toward the carbocation formation? Explain your answer.

A

Reaction (I) is more exothermic and hence more selective for carbocation formation

B

Reaction (II) is more exothermic and hence more selective for carbocation formation

C

Reaction (I) is more endothermic and hence more selective for carbocation formation

D

Reaction (II) is more endothermic and hence more selective for carbocation formation

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