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Equatorial Preference
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Equatorial Preference
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4. Alkanes and Cycloalkanes / Equatorial Preference / Problem 1
Determine whether the
cis
isomer or the
trans
isomer of the following compound is more stable.
A
The less bulky group
(iso-propyl)
is at the equatorial position and
(tert-butyl)
is at the axial position. Thus, the
trans
-conformation is more stable.
B
The bulkier group
(tert-butyl)
is at the equatorial position and
(iso-propyl)
is also at the equatorial position. Thus, the
cis
-conformation is more stable.
C
The bulkier group
(tert-butyl)
is at the equatorial position and
(iso-propyl)
is at the axial position. Thus, the
cis
-conformation is more stable.
D
The bulkier group
(tert-butyl)
is at the axial position and
(iso-propyl)
is also at the axial position. Thus, the
cis
-conformation is more stable.
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