Organic Chemistry
Radical (i) is more stable than (ii) due to the presence of a delocalized free radical via the inductive effect in (ii).
Radical (ii) is more stable than (i) due to the presence of a delocalized free radical via the resonance effect in (ii).
Radical (i) is more stable than (ii) due to the presence of alkyl groups that donate electrons via the hyperconjugation effect in (ii).
Radical (ii) is more stable than (i) due to the presence of alkyl groups that donate electrons via the electronegative effect in (i).