Enthalpy
6. Thermodynamics and Kinetics / Enthalpy / Problem 1
In the iodination of ethane shown below, tetraiodomethane (CI4) is used as the source of iodine in the presence of a free-radical initiator such as hydrogen peroxide (H2O2).
Propose a mechanism for the reaction, and determine the value of ∆H for each of the steps in your mechanism using the appropriate bond-dissociation energies.
H3C−CH3 + CI4 → H3C−CH2I + HCI3
![Table of bond-dissociation enthalpies for various bonds in kJ/mol.](https://lightcat-files.s3.amazonaws.com/problem_images/d05102b437c64eaa-1666714720799.jpg)
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