4. Alkanes and Cycloalkanes
A-Values
4:30 minutes
Problem 5.50a
Textbook Question
Textbook Question(••) The A value of a substituent on a cyclohexane ring is essentially the ∆G° for a substituent going from the equatorial to the axial position in a chair–chair interconversion. Because most substituents prefer to be in the equatorial position, A values are, by definition, positive numbers. Use the table of A values to calculate ∆G° and K_eq for the chair–chair interconversions shown. <IMAGE>
(a) <IMAGE>
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