26. Amines
Amine Alkylation
3:07 minutes
Problem 19-28
Textbook Question
Textbook QuestionAddition of one equivalent of ammonia to 1-bromoheptane
gives a mixture of heptan-1-amine, some dialkylamine, some
trialkylamine, and even some tetraalkylammonium bromide.
(a) Give a mechanism to show how this reaction takes place,
as far as the dialkylamine.
(b) How would you modify the procedure to get an
acceptable yield of heptan-1-amine?
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