26. Amines
Cope Elimination
4:59 minutes
Problem 19.22
Textbook Question
Textbook QuestionWhen the (R,R) isomer of the amine shown is treated with
an excess of methyl iodide, then silver oxide, then heated,
the major product is the Hofmann product.
(b) Some Zaitsev product is also formed. It has
the (E) configuration. When the same amine is treated
with mCPBA and heated, the Zaitsev product has
the (Z) configuration. Use stereochemical drawings
of the transition states to explain these observations.
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