Give common names for the following compounds.
(a) (CH3)2CHOCH(CH3)CH2CH3
(b) (CH3)3COCH2CH(CH3)2
(c) PhOCH2CH3
(d) ClCH2OCH2CH2CH3
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Give common names for the following compounds.
(a) (CH3)2CHOCH(CH3)CH2CH3
(b) (CH3)3COCH2CH(CH3)2
(c) PhOCH2CH3
(d) ClCH2OCH2CH2CH3
Predict the major products of the following reactions, including stereochemistry where appropriate.
a. 2,2-dimethylxirane + H+/H218O (oxygen labeled water)
b. 2,2-dimethylxirane + H18O–/H218O (oxygen labeled water)
Give the expected products of the following reactions. Include a protonation step where necessary.
(a) 2,2-dimethyloxirane + isopropylmagnesium bromide
(b) propylene oxide + n-butyllithium
(c) cyclopentyloxirane + ethyllithium
Predict the major products of the following reactions, including stereochemistry where appropriate.
(c) (2S,3R)-2-ethyl-2,3-dimethyloxirane + CH3O– / CH3OH
(d) (2S,3R)-2-ethyl-2,3-dimethyloxirane + H+ / CH3OH
Give common names for the following compounds.
(e)
(f)
Write structural formulas for the following compounds.
(g) cis-2,3-epoxyhexane
(h) (2R,3S)-2-methoxypentan-3-ol
(i) trans-2,3-dimethyloxirane