Here are the essential concepts you must grasp in order to answer the question correctly.
Solubility
Solubility is the maximum amount of a solute that can dissolve in a specific amount of solvent at a given temperature. In this case, potassium nitrate (KNO₃) has a solubility of 32 g in 100 g of water at 20 °C, meaning that this is the limit for dissolving KNO₃ in that amount of water without forming a saturated solution.
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Saturated Solution
A saturated solution occurs when the maximum amount of solute has been dissolved in a solvent at a specific temperature, resulting in any additional solute remaining undissolved. For potassium nitrate in this scenario, if 32 g is added to 100 g of water, the solution is saturated, while adding more solute would exceed this limit.
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Unsaturated Solution
An unsaturated solution is one in which less solute is dissolved than the maximum capacity at a given temperature. In the context of the question, if 32 g of KNO₃ is added to 200 g of water, the solution remains unsaturated because the solubility limit is based on the amount of water, allowing for more KNO₃ to dissolve.
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