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Ch.3 - Molecules, Compounds & Chemical Equations
Chapter 3, Problem 97

Combustion analysis of a hydrocarbon produces 33.01 g CO2 and 13.51 g H2O. Calculate the empirical formula of the hydrocarbon.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Combustion Analysis

Combustion analysis is a technique used to determine the composition of a hydrocarbon by burning it in excess oxygen. The products of this reaction are typically carbon dioxide (CO2) and water (H2O). By measuring the masses of these products, one can infer the amounts of carbon and hydrogen in the original hydrocarbon, which is essential for calculating its empirical formula.
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Empirical Formula

The empirical formula of a compound represents the simplest whole-number ratio of the elements present in that compound. It is derived from the moles of each element calculated from the mass of the products obtained in combustion analysis. This formula is crucial for understanding the basic composition of the hydrocarbon before determining its molecular structure.
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Mole Concept

The mole concept is a fundamental principle in chemistry that relates the mass of a substance to the number of particles it contains. One mole of any substance contains Avogadro's number (approximately 6.022 x 10^23) of entities, whether atoms, molecules, or ions. In combustion analysis, converting the mass of CO2 and H2O to moles allows for the determination of the number of carbon and hydrogen atoms in the hydrocarbon, which is necessary for calculating the empirical formula.
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