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Ch.15 - Chemical Equilibrium
Chapter 15, Problem 25a

H2 and I2 are combined in a flask and allowed to react according to the reaction: H2(g) + I2(g) ⇌ 2 HI(g) Examine the figures (sequential in time) and answer the questions: a. Which figure represents the point at which equilibrium is reached?

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1. The point at which equilibrium is reached in a chemical reaction is when the concentrations of the reactants and products stop changing. This means that the rate of the forward reaction (H2(g) + I2(g) -> 2 HI(g)) is equal to the rate of the reverse reaction (2 HI(g) -> H2(g) + I2(g)).
2. To determine when equilibrium is reached, you would need to examine the figures and look for the point at which the concentrations of H2, I2, and HI stop changing. This is because at equilibrium, the concentrations of the reactants and products remain constant.
3. If the figures are graphs of concentration versus time, the point at which the lines become horizontal (i.e., the slope of the line is zero) indicates that equilibrium has been reached. This is because the concentrations of the reactants and products are no longer changing.
4. If the figures are images of the flask at different points in time, you would look for the point at which the appearance of the flask stops changing. This would indicate that the concentrations of the reactants and products are no longer changing, and thus equilibrium has been reached.
5. Remember, reaching equilibrium does not necessarily mean that the concentrations of the reactants and products are equal. It simply means that their rates of reaction are equal, so the concentrations remain constant.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Chemical Equilibrium

Chemical equilibrium occurs in a reversible reaction when the rates of the forward and reverse reactions are equal, resulting in constant concentrations of reactants and products. In the given reaction, H2 and I2 combine to form HI, and at equilibrium, the amount of H2 and I2 will remain unchanged as they are converted to HI and vice versa.
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Dynamic Nature of Equilibrium

Equilibrium is dynamic, meaning that even though the concentrations of reactants and products remain constant, the reactions continue to occur in both directions. This concept emphasizes that molecules are still reacting, but the overall concentrations do not change, which is crucial for identifying the point of equilibrium in the reaction.
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Le Chatelier's Principle

Le Chatelier's Principle states that if a system at equilibrium is disturbed by changes in concentration, temperature, or pressure, the system will adjust to counteract the disturbance and restore a new equilibrium. Understanding this principle helps predict how changes in conditions will affect the position of equilibrium in the reaction between H2, I2, and HI.
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Related Practice
Textbook Question

Find and fix each mistake in the equilibrium constant expressions. b. CO(g) + Cl2(g) ⇌ COCl2(g) K = [CO][Cl2]/[COCl2]

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Textbook Question

When this reaction comes to equilibrium, will the concentrations of the reactants or products be greater? Does the answer to this question depend on the initial concentrations of the reactants and products? A(g)+B(g) ⇌ 2 C(g) Kc = 1.4⨉10-5

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Textbook Question

Ethene (C2H4) can be halogenated by this reaction: C2H4(g) + X2(g) ⇌ C2H4X2(g) where X2 can be Cl2 (green), Br2 (brown), or I2 (purple). Examine the three figures representing equilibrium concentrations in this reaction at the same temperature for the three different hal- ogens. Rank the equilibrium constants for the three reactions from largest to smallest.

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Textbook Question

A chemist trying to synthesize a particular compound attempts two different synthesis reactions. The equilibrium constants for the two reactions are 23.3 and 2.2⨉104 at room temperature. However, upon carrying out both reactions for 15 minutes, the chemist finds that the reaction with the smaller equilibrium constant produces more of the desired product. Explain how this might be possible.

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Textbook Question

This reaction has an equilibrium constant of Kp = 2.26⨉104 at 298 K. CO(g) + 2 H2(g) ⇌ CH3OH(g) Calculate Kp for each reaction and predict whether reactants or products will be favored at equilibrium. a. CH3OH(g) ⇌ CO(g) + 2 H2(g)

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Textbook Question

This reaction has an equilibrium constant of Kp = 2.26⨉104 at 298 K. CO(g) + 2 H2(g) ⇌ CH3OH(g) Calculate Kp for each reaction and predict whether reactants or products will be favored at equilibrium.

b. 1/2 CO(g) + H2 (g) ⇌ 1/2 CH3OH(g)

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