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Ch.11 - Liquids, Solids & Intermolecular Forces
Chapter 11, Problem 36d

Determine the kinds of intermolecular forces that are present in each element or compound. d. HF

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Step 1: Identify the type of molecule. HF is a polar molecule because it is made up of two different elements, Hydrogen and Fluorine, which have different electronegativities.
Step 2: Identify the types of intermolecular forces. There are three types of intermolecular forces: London dispersion forces, dipole-dipole interactions, and hydrogen bonding.
Step 3: Determine which forces are present. All molecules have London dispersion forces. Since HF is a polar molecule, it also has dipole-dipole interactions.
Step 4: Check for hydrogen bonding. Hydrogen bonding is a special type of dipole-dipole interaction that occurs when hydrogen is bonded to a highly electronegative atom (N, O, or F). In HF, hydrogen is bonded to fluorine, so hydrogen bonding is present.
Step 5: Summarize the types of intermolecular forces present in HF. HF has London dispersion forces, dipole-dipole interactions, and hydrogen bonding.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Intermolecular Forces

Intermolecular forces are the attractive forces between molecules that influence physical properties such as boiling and melting points. They include hydrogen bonding, dipole-dipole interactions, and London dispersion forces. Understanding these forces is crucial for predicting how substances behave in different states and conditions.
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Hydrogen Bonding

Hydrogen bonding is a specific type of strong dipole-dipole interaction that occurs when hydrogen is covalently bonded to highly electronegative atoms like nitrogen, oxygen, or fluorine. In the case of HF (hydrogen fluoride), the hydrogen atom forms a hydrogen bond with the fluorine atom of another HF molecule, significantly affecting its properties, such as its high boiling point compared to other similar-sized molecules.
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Polarity

Polarity refers to the distribution of electrical charge over the atoms in a molecule. A polar molecule has a significant difference in electronegativity between its atoms, leading to a dipole moment. HF is a polar molecule due to the high electronegativity of fluorine compared to hydrogen, which results in strong intermolecular forces and influences its interactions with other molecules.
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