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Ch.4 - Reactions in Aqueous Solution

Chapter 4, Problem 6

Which of the following ions will always be a spectator ion in a precipitation reaction? (a) Cl- (b) NO3- (c) NH4+ (d) S2- (e) SO42-

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Welcome back everyone to another video which of the following ions will always be a spectator ion in a precipitation reaction. A chloride anion B nitrate anion C barium cion D carbonate anion and E lead to cion. We got five answer choices which basically correspond to the previously indicated choices. Now, let's think about this problem in terms of solubility rules. Let's start with a chloride anion. And let's remember that according to the solubility rules, the majority of chlorides are soluble except from, let's say as an example, silver chloride, we know that this is a precipitate, right? Or we can also take lead two chloride. This is also a precipitate as well as mercury two chloride. OK. So what we know is that if chloride anion can form precipitates, then it will not necessarily be a spectator ion all the time because iron Spectators are a result of a reaction in which we can actually cancel them out and they are not forming a precipitate in an ionic compound. Now, let's think about nitrates and according to the solubility rules, we can say that all nitrates are soluble. In other words, it doesn't really matter what kind of a cion we take whenever we form a salt with nitrate, such as salt will be soluble in water. So B is our first candidate for the correct answer, right? We want to label it so far. Now C we have barium Canion and in this case, let's simply remember our classical precipitate barium sulfate. It's a solid, right? It's white precipitate. It's a group to two A element which forms precipitates with sulfates and carbonates. Herbarium cannot always be a spectator iron because it forms insoluble salts. D carbonate. Once again, a lot of carbonates are soluble. But as previously indicated, we can have barium carbonate for instance, which is a solid, right group. Two A elements tend to form in soluble carbonates. We can also take calcium carbonate, which is a classical example. And as a result due to the fact that carbonate can form insoluble told it will not necessarily be an honest spectator. Now, e led to cion, we already know that lead can form lead to chloride, which is insoluble at lower temperatures, right? Or for example, lead to sulfate because those are solids. Let two cion is unlikely to be an iron spectator. So the only option from this list is nitrate, it will always act as a spectator ion. And we can conclude that the correct answer to this problem is option B nitrate anion is likely to be a spectator iron or more accurately speaking, it will always be a spectator iron in a precipitation reaction. Thank you for watching.
Related Practice
Textbook Question

Use the molecular representations shown here to classify each compound as a nonelectrolyte, a weak electrolyte, or a strong electrolyte (see Figure 4.6 for the element color scheme). (a)

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Textbook Question

The concept of chemical equilibrium is very important. Which one of the following statements is the most correct way to think about equilibrium? (a) If a system is at equilibrium, nothing is happening. (b) If a system is at equilibrium, the rate of the forward reaction is equal to the rate of the back reaction. (c) If a system is at equilibrium, the product concentration is changing over time.

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Textbook Question

You are presented with a white solid and told that due to careless labeling it is not clear if the substance is barium chloride, lead chloride, or zinc chloride. When you transfer the solid to a beaker and add water, the solid dissolves to give a clear solution. Next an Na2SO41aq2 solution is added and a white precipitate forms. What is the identity of the unknown white solid?

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Textbook Question

Which of these statements is true?

a. If a compound is oxidized, it is gaining electrons.

b. If a base is neutralized, it is gaining protons.

c. Elements that are metals cannot be oxidized.

d. If hydrogen gas is generated in a reaction, it must be an acid–base reaction.

Textbook Question

What kind of reaction is this? N2(g)+3H2(g)⟶2NH3(g)

a. an acid–base reaction

b. a metathesis reaction

c. a redox reaction

d. a precipitation reaction

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Textbook Question

An aqueous solution contains 1.2 mM of total ions. (a) If the solution is NaCl(aq), what is the concentration of chloride ion?

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