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Ch.9 - Molecular Geometry and Bonding Theories

Chapter 9, Problem 101d

In ozone, O3, the two oxygen atoms on the ends of the molecule are equivalent to one another. (d) How many electrons are delocalized in the p system of ozone?

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Hello everyone in this video. We're going to determine the number of the localized electrons and the price system of format. So let's first start off by drawing the LewiS structure for format. It's going to have a central atom of carbon Singapore into a hydrogen. Take up to an oxygen. Of course it has three lone pairs Wearing a formal church and double bonded to an oxygen with two phone pairs. Alright, so of course there's going to be resident structures. The structures in a different color to our first breed. Draw the lower structure for this for meat. So the carbon bond to an oxygen with two lone pairs, single bond to one oxygen With three lone pairs and a hydrogen. Alright, so join the arrow, pushing so we'll have one of them, the loan paris here come and make a double bond here and then we'll have one of these pie pons. Go ahead and break off to make a long pair. So be something like this because of that sense. We'll have our resident structure to look like this. So these are our resonance structures. And this present structure involves one C. O bond or pi bond and one long pair from the oxygen to do this long to do this resonant structure. So the C. O bond here and this long pair here of oxygen. So the pi bond is of course two electrons and then a lone pair has two electrons. So the pi bond that we're dealing with from the carbon and oxygen here that has two electrons. And then the lone pair. So they lone pair from this oxygen here. First that's going to have two electrons as well, So two plus 2, It goes to four. So that's a total of four total de localized electrons. So our answer here is four. Do you localized electrons? Because the two electrons from the pi bond and the two electrons from our lone pair are what are being used to create our resident structure. And so this is the final answer for this problem.
Related Practice
Textbook Question

Which of the following statements about hybrid orbitals is or are true? (i) After an atom undergoes sp hybridization, there is one unhybridized p orbital on the atom, (ii) Under sp2 hybridization, the large lobes point to the vertices of an equilateral triangle, and (iii) The angle between the large lobes of sp3 hybrids is 109.5°.

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Textbook Question

Sodium azide is a shock-sensitive compound that releases N2 upon physical impact. The compound is used in automobile airbags. The azide ion is N3-. (a) Draw the Lewis structure of the azide ion that minimizes formal charge (it does not form a triangle). Is it linear or bent?

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Textbook Question

Sodium azide is a shock-sensitive compound that releases N2 upon physical impact. The compound is used in automobile airbags. The azide ion is N3-. (b) State the hybridization of the central N atom in the azide ion.

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Textbook Question

Butadiene, C4H6, is a planar molecule that has the following carbon–carbon bond lengths:

(a) Predict the bond angles around each of the carbon atoms and sketch the molecule.

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Textbook Question

Butadiene, C4H6, is a planar molecule that has the following carbon–carbon bond lengths:

(b) From left to right, what is the hybridization of each carbon atom in butadiene?

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Textbook Question

Butadiene, C4H6, is a planar molecule that has the following carbon–carbon bond lengths:

(c) The middle C¬C bond length in butadiene (1.48 Å) is a little shorter than the average C¬C single bond length (1.54 Å). Does this imply that the middle C¬C bond in butadiene is weaker or stronger than the average C¬C single bond?

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