The structural formulas of the compounds n-butane and isobutane are shown below. (c) Which formulas—empirical, molecular, or structural—allow you determine these are different compounds?
Ch.2 - Atoms, Molecules, and Ions
Chapter 2, Problem 48
Two substances have the same molecular and empirical formulas. Does this mean that they must be the same compound?
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Molecular Formula
The molecular formula of a compound indicates the actual number of atoms of each element present in a molecule. It provides specific information about the composition of the compound, such as C6H12O6 for glucose, which shows that there are six carbon, twelve hydrogen, and six oxygen atoms in each molecule.
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Empirical Formula
The empirical formula represents the simplest whole-number ratio of the elements in a compound. For example, the empirical formula for glucose (C6H12O6) is CH2O, indicating that for every carbon atom, there are two hydrogen atoms and one oxygen atom, regardless of the actual number of atoms in the molecule.
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Isomerism
Isomerism occurs when two or more compounds have the same molecular and empirical formulas but differ in the arrangement of atoms or the connectivity of their structures. These variations can lead to different physical and chemical properties, meaning that compounds with identical formulas can still be distinct substances.
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Ball-and-stick representations of benzene, a colorless liquid often used in organic chemistry reactions, and acetylene, a gas used as a fuel for high-temperature welding, are shown below. (a) Determine the molecular formula of each.
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What are the molecular and empirical formulas for each of the following compounds? Write the molecular formula for the following compound.
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Write the empirical formula corresponding to each of the following molecular formulas: (a) Al2Br6
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Write the empirical formula corresponding to each of the following molecular formulas: (b) C8H10
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Textbook Question
Write the empirical formula corresponding to each of the following molecular formulas: (c) C4H8O2
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