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Ch.2 - Atoms, Molecules, and Ions
Chapter 2, Problem 48

Two substances have the same molecular and empirical formulas. Does this mean that they must be the same compound?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Molecular Formula

The molecular formula of a compound indicates the actual number of atoms of each element present in a molecule. It provides specific information about the composition of the compound, such as C6H12O6 for glucose, which shows that there are six carbon, twelve hydrogen, and six oxygen atoms in each molecule.
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Empirical Formula

The empirical formula represents the simplest whole-number ratio of the elements in a compound. For example, the empirical formula for glucose (C6H12O6) is CH2O, indicating that for every carbon atom, there are two hydrogen atoms and one oxygen atom, regardless of the actual number of atoms in the molecule.
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Isomerism

Isomerism occurs when two or more compounds have the same molecular and empirical formulas but differ in the arrangement of atoms or the connectivity of their structures. These variations can lead to different physical and chemical properties, meaning that compounds with identical formulas can still be distinct substances.
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